chemical engineering thermodynamics for chemical chemical engineering Mcqs
454. A closed system is cooled reversibly from 100C to 50C. If no work is done on the system________________?
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A. its internal energy (U) decreases and its entropy (S) increases

B. U and S both decreases

C. U decreases but S is constant

D. U is constant but S decreases

455. For an ideal gas, the chemical potential is given by______________?
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A. R d ln f

B. None of these

C. RT d ln P

D. R d ln P

459. The Maxwell relation derived from the differential expression for the Helmholtz free energy (dA) is________________?
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A. (?T/?V)S = (?P/?S)V

B. (?S/?P)T = (?V/?T)P

C. (?S/?V)T = (?P/?T)V

D. (?V/?S)P = (?T/?P)S

461. Which of the following is not an equation of state ?
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A. Bertholet equation

B. Clausius-Clapeyron equation

C. None of these

D. Beattie-Bridgeman equation

466. Partial molar free energy of an element A in solution is same as its__________________?
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A. Fugacity

B. Chemical potential

C. Activity co-efficient

D. Activity

467. Pick out the correct statement?
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A. The available energy in an isolated system for all irreversible (real) processes decreases

B. nge in Helmholtz free energy

C. All A, B. and C

D. The efficiency of a Carnot engine increases, if the sink temperature is decreased

E. The reversible work for compression in non-flow process under isothermal condition is the

468. Pick out the extensive property out of the following ?
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A. Free energy

B. Surface tension

C. Refractive index

D. Specific heat

471. Pick out the wrong statement?
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A. An equation relating pressure, volume and temperature of a gas is called ideal gas equation

B. Troutons ratio of non-polar liquids is calculated using Kistyakowsky equation

C. Thermal efficiency of a Carnot engine is always less than 1

D. None of these

472. Which of the following is not correct for a reversible adiabatic process ?
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A. None of these

B. PV? = constant

C. TV?-1 = constant

D. p1-?.TY = constant

473. Entropy of the system decreases, when_______________?
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A. Snow melts into water

B. A gas expands spontaneously from high pressure to low pressure

C. Water is converted into ice

D. Both B. & C
474. Pick out the correct statement ?
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A. In an isothermal system, irreversible work is more than reversible work

B. Matter and energy cannot be exchanged with the surroundings in a closed system

C. Under reversible conditions, the adiabatic work is less than isothermal work

D. Heat, work, enthalpy and entropy are all state functions

475. Claude gas liquefaction process employs cooling___________________?
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A. By expansion in an engine

B. None of these

C. At constant pressure

D. By throttling

476. Which is not a refrigerant ?
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A. NH3

B. CCl2F2

C. SO2

D. C2H4Cl2
477. The activity of an ideal gas is numerically ____________ its pressure?
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A. Data insufficient, cant be predicted

B. More than

C. Less than

D. Equal to
479. After throttling, gas temperature___________________?
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A. Increases

B. Remain same

C. May increase or decrease; depends on the nature of the gas

D. Decreases
480. Boiling of liquid is accompanied with increase in the__________________?
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A. Specific entropy

B. Vapor pressure

C. All (A), B. and (C)

D. Specific Gibbs free energy

485. Heat pump_______________________?
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A. Accomplishes only space heating in winter

B. Accomplishes only space cooling in summer

C. Accomplishes both A. and B

D. Works on Carnot cycle

486. With increase in temperature, the internal energy of a substance___________________?
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A. Remains unchanged

B. Decreases

C. May increase or decrease; depends on the substance

D. Increases
488. Clausius-Clapeyron equation is applicable to _____________ equilibrium processes?
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A. All A, B. and C

B. Solid-vapor

C. Liquid-vapor

D. Solid-liquid

489. Maxwells relation corresponding to the identity, dH = dS = Vdp + ??i dni is_____________________?
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A. (?T/?V)S, ni = -(?P/?S)V, ni

B. (?T/?P)S, ni = (?V/?S)P, ni

C. (?S/?V)T, ni = (?P/?T)V, ni

D. (?S/?P)T, ni = (?V/?T)P, ni

491. Pick out the wrong statement ?
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B. An ideal liquid or solid solution is defined as one in which each component obeys Raoults

C. If Raoults law is applied to one component of a binary mixture; Henrys law or Raoults law is

D. None of these

E. lied to the other component also

F. Henrys law is rigorously correct in the limit of infinite dilution

492. Work done is a____________________?
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A. Path function

B. Point function

C. State description of a system

D. Property of the system

494. Enthalpy H is defined as___________________?
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A. None of these

B. H E = PV

C. H = E PV

D. H = F TS

496. The thermodynamic law, PVy = constant, is not applicable in case of______________?
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A. Free expansion of an ideal gas

B. Adiabatic expansion of steam in a turbine

C. Ideal compression of air

D. Adiabatic compression of a perfect gas

498. Pick out the wrong statement?
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A. Cp of monatomic gases such as metallic vapor is about 5 kcal/kg.atom

B. At absolute zero temperature, the heat capacity for many pure crystalline substances is zero

C. The heat capacity of solid inorganic substance is exactly equal to the heat capacity of the

D. stance in the molten state</strong>

E. There is an increase in entropy, when a spontaneous change occurs in an isolated system